SFB 1176 • Molekulare Strukturierung weicher Materie

Project B2 • Sequence-Controlled Growth of Cross-Linked Polymer Layers on Surfaces

In this project methods for the iterative functionalization of surfaces, with a particular focus on graphite, will be developed, to enable the growth of a sequence of functional and defined covalently bonded layers orthogonal to the substrate. Hence, the project seizes the idea of a monomer based sequence controlled growth along the chain and transfers it into the second dimension. Therefore, specially synthesized poly-ene and poly-yne monomers will be linked iteratively to polythiols in thiol-ene and thiol-yne reactions to control parameters such as polarity, mesh size of the network or the attachment of functional groups.

 

Publications 2018
Title Author Source

Moock, D. S.; Steinmüller, S. O.; Wessely, I. D.; Llevot, A.; Bitterer, B.; Meier, M. A. R.; Bräse, S.; Ehrenberg, H.; Scheiba, F.

ACS Appl. Mater. Interfaces, 2018, 10, 24172-24180.

Publications 2017
Title Author Source

Llevot, A.; Steinmüller, S. O.; Bitterer, B.; Berson, J.; Wahlheim, S.; Schimmel, T.; Bräse, S.; Scheiba, F.; Meier, M. A. R.:

Polym. Chem., 2017, 8, 5824-5828.

Ridder, B.; Mattes, D. S.; Nesterov-Mueller, A.; Breitling, F.; Meier, M. A. R.;

Chem. Commun., 2017, 53, 5553-5556.

Publications 2016